The docbook mailing list is for discussions related to tools, such as using the stylesheets to publish HTML/PDF output; that is, about processing DocBook source documents, as opposed to a authoring or markup-specific question (which is what the DocBookMailingList is for). It's probably safe to say that more discussions take place on the DocBookAppsMailingList than on the docbook list, because there tend to be a lot more publishing/tools questions and discussions related to DocBook than there are authoring/markup questions.
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